Rayquaza: catchable only after you beat the Elite Four
Groundon: only catchable in Pokemon Ruby after the incident in Sootopolis
Kyogre: only catchable in Pokemon Sapphire after the incidnt in Sootopolis
Latios: is a wild pokemon after you beat the Elite four in Pokemon Ruby only/Eon ticket in Pokemon Sapphire
Latias: is a wild pokemon after you beat the Elite Four in
Pokemon Sapphire only/Eon ticket in Pokemon Ruby
Registeel: in the Ancient Tomb after you solve the chamber
Regirock: in the Desert Ruins after you solve the chamber
Regice: in the Island cove after you solve the chamber
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Rayquaza: catchable only after you beat the Elite Four
Groundon: only catchable in Pokemon Ruby after the incident in Sootopolis
Kyogre: only catchable in Pokemon Sapphire after the incidnt in Sootopolis
Latios: is a wild pokemon after you beat the Elite four in Pokemon Ruby only/Eon ticket in Pokemon Sapphire
Latias: is a wild pokemon after you beat the Elite Four in
Registeel: in the Ancient Tomb after you solve the chamber
Regirock: in the Desert Ruins after you solve the chamber
Regice: in the Island cove after you solve the chamber